Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system
The reaction of diallyl disulfide with alkyl halides in the alkali-metal hydroxide-DMSO superbasic system leads to the formation of 1-alkylthio-3-allylthio-1-propenes and 1,3-di(alkylthio)propenes. The effects of the structure of the alkyl halides, the nature of the alkali-metal cations, the halogen, and the reaction conditions on the yield and ratio of the products were investigated
Article, 1986